Stereochemistry of α‐parinaric acid fromImpatiens edgeworthii seed oil
- 1 July 1966
- Vol. 1 (4), 263-267
- https://doi.org/10.1007/bf02531613
Abstract
α-Parinaric acid is a major constituent fatty acid (48%) fromImpatiens edgeworthii Hook F. seed oil. Partial hydrazine reduction of the tetraene gave products which permit defining the stereochemistry of α-parinaric acid. Its structure iscis-9,trans-11,trans-13,cis-15-octadecatetraenoic acid. The tetraene readily reacts with maleic anhydride to give the Diels-Alder product with notrans-unsaturation. The formation of this adduct is contrary to previous reports.This publication has 13 references indexed in Scilit:
- Partial reduction of ॅ‐Eleostearic acid with hydrazineJournal of Oil & Fat Industries, 1965
- OZONOLYSIS OF UNSATURATED FATTY ACIDS: I. OZONOLYSIS OF OLEIC ACIDCanadian Journal of Chemistry, 1961
- Methyl punicate,Alpha andBeta eleostearate.Cis, trans isomerism and structureJournal of Oil & Fat Industries, 1961
- The determination of conjugatedcis‐trans andtrans‐trans methyl octadecadienoates by infrared spectrometryJournal of Oil & Fat Industries, 1959
- Zur Stereochemie der vierfach konjugiert‐ungesättigten ParinarsäurenEuropean Journal of Inorganic Chemistry, 1959
- 311. Lipids. Part VI. Total synthesis of α- and β-elæostearic and punicic (trichosanic) acidJournal of the Chemical Society, 1957
- PERIODATE–PERMANGANATE OXIDATIONS: V. OXIDATION OF LIPIDS IN MEDIA CONTAINING ORGANIC SOLVENTSCanadian Journal of Chemistry, 1956
- 4. The seed fat of Parinarium laurinum. Part I. Component acids of the seed fatJournal of the Chemical Society, 1950
- Über das Vorkommen von Parinarsäure und Essigsäure in den Samenfetten der BalsaminaceenEuropean Journal of Inorganic Chemistry, 1948
- 170. Unsaturated acids of natural oils. Part II. The highly unsaturated acid of the kernels of Parinarium laurinumJournal of the Chemical Society, 1935