Calcined MgAICO3-HT Catalysed Cyanosilylation of Carbonyl Compounds and Nucleophilic Ring Opening of Oxiranes Using TMSCN
- 1 September 1995
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 25 (18), 2829-2836
- https://doi.org/10.1080/00397919508011830
Abstract
Nucleophilic addition of TMSCN to carbonyl compounds is found to be catalysed efficiently using hydrotalcite as a solid base. The catalyst is also found to be active in the nucleophilic ring opening of oxiranes giving high regioselectivity.Keywords
This publication has 10 references indexed in Scilit:
- A Novel Hydroperoxidation of Aralkanes Using Calcined ZnCrCO3-HTlc+Synlett, 1994
- Hydrotalcite-type anionic clays: Preparation, properties and applications.Catalysis Today, 1991
- Efficient Solid Catalyst Systems for Cyanosilylation of Carbonyl Compounds with CyanotrimethylsilaneChemistry Letters, 1989
- Solid-supported sodium azide reagents: their preparation and reactions with epoxidesThe Journal of Organic Chemistry, 1989
- Lanthanides as lewis-acid catalysts in aldol addition,cyanohydrin-forming and oxirane ring opening reactionsTetrahedron Letters, 1987
- Catalytic reactions by thermally activated, synthetic, anionic clay mineralsJournal of Catalysis, 1985
- The Polymerization of β-Propiolactone by Calcined Synthetic HydrotalciteBulletin of the Chemical Society of Japan, 1979
- Cyanosilylation of aldehydes and ketones. A convenient route to cyanohydrin derivativesJournal of the Chemical Society, Chemical Communications, 1973
- Carbonyl insertion reactions of silicon pseudohalides: CatalysisTetrahedron Letters, 1973
- Reaktion von aldehyden mit trimethylsilylazidTetrahedron Letters, 1967