The influence of paramagnetic molecules on singlet-triplet transitions
- 1 January 1960
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 3 (1), 67-70
- https://doi.org/10.1080/00268976000100071
Abstract
It is shown that singlet-triplet transitions may obtain a finite probability when exchange interaction occurs between the absorbing molecule and a paramagnetic molecule. According to this mechanism no quantitative relation exists between the transition dipole strength and the paramagnetic susceptibility of the perturbing molecule.Keywords
This publication has 4 references indexed in Scilit:
- Modes of energy transfer from excited and unstable ionized states. Intramolecular and intermolecular energy conversion involving change of multiplicityDiscussions of the Faraday Society, 1959
- Magnetic Perturbation of the Lowest Triplet States of Aromatic Molecules by Dissolved OxygenNature, 1956
- Molecular complexes and their spectra. VI. Some problems and new developmentsRecueil des Travaux Chimiques des Pays-Bas, 1956
- Collisional Perturbation of Spin-Orbital Coupling and the Mechanism of Fluorescence Quenching. A Visual Demonstration of the PerturbationThe Journal of Chemical Physics, 1952