Inorganic–organic hybrid materials: construction of the first polymeric channelled halometallate(ii) system

Abstract
A macrocyclic ammonium cation (LH)+ (L = 1-aza-4,10-dithia-7-oxacyclododecane) has been used to control the assembly of a [PbCl3 ] polymeric anion within the inorganic–organic hybrid compound (LH) PbCl3 that adopts an unprecedented structure.

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