The rearrangement of coordinated η2-vinyl ligands into η3-allyl and alkylidyne species
- 1 January 1990
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1330-1332
- https://doi.org/10.1039/c39900001330
Abstract
Details of the rearrangement of the η2-vinyl complex [[graphic omitted]Me(Ph)}{P(OMe)3}2(η-C5H5)]1 to the η3-allyl species [Mo{η3-CH2C(Ph)CH(Ph)}{P(OMe)3}2(η-C5H5)]2a, 2b, and of [[graphic omitted]H(Ph)}(CO)(PMe2Ph)(η-C5H5)]3 into [Mo{CCHPh2}(CO)(PMe2Ph)(η-C5H5)]4, are described together with a crystal structure determination of 2b and possible mechanistic pathways.Keywords
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