ASYMMETRIC OXIDATION OF OLEFINS WITH OSMIUM TETROXIDE COORDINATED BY CHIRAL DIAMINES DERIVED FROM L-TARTARIC ACID
- 5 January 1986
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 15 (1), 131-134
- https://doi.org/10.1246/cl.1986.131
Abstract
The enantioselective oxidation of olefins with OsO4 coordinated by chiral diamines derived from L-tartaric acid is described. Phenylketene dimethylacetal and trans-stilbene are converted to (R)-methyl mandelate and (1R,2R)-1,2-diphenyl-1,2-ethanediol with moderate and high enantioselectivity, respectively.This publication has 8 references indexed in Scilit:
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