Raman spectroscopy of graphite
Top Cited Papers
- 14 September 2004
- journal article
- review article
- Published by The Royal Society in Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences
- Vol. 362 (1824), 2271-2288
- https://doi.org/10.1098/rsta.2004.1454
Abstract
We present a review of the Raman spectra of graphite from an experimental and theoretical point of view. The disorder–induced Raman bands in this material have been a puzzling Raman problem for almost 30 years. Double–resonant Raman scattering explains their origin as well as the excitation–energy dependence, the overtone spectrum and the difference between Stokes and anti–Stokes scattering. We develop the symmetry–imposed selection rules for double–resonant Raman scattering in graphite and point out misassignments in previously published works. An excellent agreement is found between the graphite phonon dispersion from double–resonant Raman scattering and other experimental methods.Keywords
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