Phase-space theory of electron detachment in slow atomic collisions

Abstract

A classical phase‐space theory for the excitation of electrons in slow atomic collisions is presented. An equation which governs the energy transfer between the electron and the heavy particles is derived for slow collisions (adiabatic approximation). This equation is analogous to the first law of thermodynamics for an open system. The theory contains only one adjustable parameter and gives excellent correlation for existing experimental measurements of detachment rate coefficients of F⁻ + (Ar, N₂, CO) and Br⁻ + Ar. Possible modifications to the present theory are summarized. It is anticipated that the theory should be applicable to other electronic rate processes such as ionization and charge transfer.