Infrared Spectrum of Co(CO)3NO
- 1 February 1961
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 34 (2), 530-534
- https://doi.org/10.1063/1.1700979
Abstract
The infrared spectra of Co(CO)3N14O and Co(CO)3N15O vapor are reported from 10 000 to 280 cm−1 and all fundamentals assigned. The two C–O stretches and the N–O stretch are at 2108, 2047, and 1822 cm−1, respectively. Exchange with C13O indicates that a strong band at 2010 cm−1 is due to the C13–O stretch of the isotopic species Co(CO)2(C13O)NO. A normal coordinate treatment has been carried out, and the force constants determined.Keywords
This publication has 13 references indexed in Scilit:
- The valence-type force constants of nickel tetracarbonylSpectrochimica Acta, 1959
- Vibrational Spectrum of Nickel CarbonylThe Journal of Chemical Physics, 1958
- Infrared Spectroscopy from 5 to 200 Microns with a Small Grating Spectrometer*Journal of the Optical Society of America, 1957
- Dicobalt OctacarbonylPublished by Wiley ,1957
- Infrared Spectrum of Ni(CO)4 VaporThe Journal of Chemical Physics, 1955
- The Calibration of Infrared Prism SpectrometersJournal of the Optical Society of America, 1953
- Conversion of Isotopically Enriched CO 2 to COScience, 1947
- Dicobalt Octacarbonyl, Cobalt Nitrosyl Tricarbonyl, and Cobalt Tetracarbomyl HydridePublished by Wiley ,1946
- The Vibrational Spectrum and Thermodynamic Properties of Nickel CarbonylThe Journal of Chemical Physics, 1938
- VI.—The action of nitric oxide on the metallic carbonylsJournal of the Chemical Society, Transactions, 1922