The crystal structure of an octahedral high-spin Mn III complex, acetylacetonatobis-(N-phenylaminotroponiminato)manganese(III)

Abstract

The crystal structure of acetylacetonatobis-(N-phenylaminotroponiminato)manganese(III) has revealed the first distorted octahedral complex of high-spin Mn^III and has suggested empirical rules for predicting the final configurations of octahedral Cu^II and Mn^III compounds.