Mobility of Ions in LiquidI andas a Function of Pressure and Temperature
- 15 June 1962
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 126 (6), 1927-1934
- https://doi.org/10.1103/physrev.126.1927
Abstract
In this paper we present an experimental study of the pressure and temperature dependence of the mobility of the positive and negative species of charged particles in liquid above the transition and in liquid . The mobility of the positive species in decreases linearly with increasing density, and the Stokes radius of the positive species is inversely proportional to . The mobility of the negative species initially increases with increasing density and then falls off linearly with further increase in density. The Stokes radius of the negative species increases with increasing temperature. At constant density the mobilities of both species in and vary very slowly with temperature. At the vapor pressure and around 2.2°K there is a larger temperature dependence than indicated above, but this is probably due to the approach of the transition. The mobility of the positive species in and at 3.0°K is a linear function of density, independent of the isotope.
Keywords
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