Deuterated Water Effects on Acid Ionization Constants
- 22 March 1963
- journal article
- other
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 139 (3560), 1198-1203
- https://doi.org/10.1126/science.139.3560.1198
Abstract
Linear relations of the form ΔpK = pKD - pKH = a + b pKH relating ionization constants of acids in light and heavy water must have the same slope b for any kind of acid unless the previously unconsidered charge type is important or this equation is not valid.Keywords
This publication has 4 references indexed in Scilit:
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- DEUTERIUM ISOTOPE EFFECTS ON DISSOCIATION CONSTANTS AND FORMATION CONSTANTS1The Journal of Physical Chemistry, 1961
- Acidity Constants of Some Hammett Indicators in Heavy Water. The Hammett Acidity Function, D0, for DCl and D2SO4 Solutions1Journal of the American Chemical Society, 1960
- IONIZATION OF INDIVIDUAL GROUPS IN DIBASIC ACIDS, WITH APPLICATION TO THE AMINO AND HYDROXYL GROUPS OF TYROSINEProceedings of the National Academy of Sciences, 1958