C−H-Activated Aluminum Hydroxide via Molecular Oxygen
- 4 February 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 45 (5), 1912-1914
- https://doi.org/10.1021/ic0600230
Abstract
The reaction of LAl[η2-(C2(SiMe3)2)] (1; L = HC[(CMe)(NDipp)]2, Dipp = 2,6-iPr2C6H3) with dioxygen leads to the elimination of bis(trimethylsilyl)acetylene and the formation of the corresponding aluminum monohydroxide via the oxidation of one of the CHMe2 groups on the Dipp ring.This publication has 12 references indexed in Scilit:
- The Selective Preparation of an Aluminum Oxide and Its Isomeric C−H-Activated HydroxideJournal of the American Chemical Society, 2005
- Reversible O−O Bond Cleavage and Formation of a Peroxo Moiety of a Peroxocarbonate Ligand Mediated by an Iron(III) ComplexJournal of the American Chemical Society, 2005
- Reaction of LAlH2 with tert-Butyl Hydrogenperoxide under C−H Bond Activation and Substitution Leads to the Formation of a Pentacoordinated tert-Butylperoxo Aluminum CompoundInorganic Chemistry, 2005
- The Renaissance of Aluminum ChemistryInorganic Chemistry, 2004
- A Seven-Membered Aluminum Sulfur Allenyl Heterocycle Arising from the Conversion of an Aluminacyclopropene with CS2Journal of the American Chemical Society, 2004
- Aluminum Dihydroxide with Terminal OH Groups: An Unprecedented Congener of Boronic AcidAngewandte Chemie International Edition, 2003
- Oxygen−Oxygen Bond Homolysis in a Novel Titanium(IV) Alkylperoxide Complex, Cp2Ti(OOtBu)ClJournal of the American Chemical Society, 2002
- Facile Synthesis of Cyclopropene Analogues of Aluminum and an Aluminum Pinacolate, and the Reactivity of LAl[η2-C2(SiMe3)2] toward Unsaturated Molecules (L = HC[(CMe)(NAr)]2, Ar = 2,6-i-Pr2C6H3)Journal of the American Chemical Society, 2001
- π-Bonding and the Lone Pair Effect in Multiple Bonds between Heavier Main Group ElementsChemical Reviews, 1999
- Selective epoxidation of olefins by oxo[N-(2-oxidophenyl)salicylidenaminato]vanadium(V) alkylperoxides. On the mechanism of the Halcon epoxidation processJournal of the American Chemical Society, 1986