Quadrupole Coupling of the Deuteron in DCCCl and DCN

1 February 1955

journal article
research article
Published by AIP Publishing in The Journal of Chemical Physics

Vol. 23 (2), 253-255
https://doi.org/10.1063/1.1741950

Abstract

The quadrupole coupling of the deuteron (eqQ) _D was measured in DCCCl where it was found to be +175±20 kc/sec. A less accurate determination of the absolute value (eqQ) _D in DCN yielded approximately 290 kc/sec. The field gradient, q, at the deuterium nucleus in DCCCl is +8.85±10 percent×10¹⁴ esu. A calculation of q based on a Hund‐Mulliken molecular model yields a q of the same sign as that observed but approximately twice as large, indicating the insufficiency of the model for such detailed calculations.

Keywords

This publication has 11 references indexed in Scilit:

An Ultra-High-Frequency Rotational Line of HDO
Physical Review B, 1953
The Quadrupole Moment of ${Li}^{7}$
Physical Review B, 1953
Nuclear Radiofrequency Spectra of $H_{2}$ and $D_{2}$ in High and Low Magnetic Fields
Physical Review B, 1952
The Deuteron Quadrupole Moment and the Radiofrequency Spectra of $H_{2}$ and $D_{2}$ in Low Magnetic Fields
Physical Review B, 1951
Radiofrequency Spectrum of $D_{2}$ in a Magnetic Field
Physical Review B, 1950
Formulas and Numerical Tables for Overlap Integrals
The Journal of Chemical Physics, 1949
Determination of Electronic Structure of Molecules from Nuclear Quadrupole Effects
The Journal of Chemical Physics, 1949
Calculation of Nuclear Quadrupole Effects in Molecules
Physical Review B, 1948
An Electrical Quadrupole Moment of the Deuteron The Radiofrequency Spectra of HD and $D_{2}$ Molecules in a Magnetic Field
Physical Review B, 1940
Atomic Shielding Constants
Physical Review B, 1930

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