Time dependence of forces between mica surfaces in water and its relation to the release of surface ions

Abstract

A surface force balance has been used to investigate the time-dependent behavior of the normal forces between two smooth mica surfaces immersed in salt-free (conductivity) water. A long-ranged repulsion on initial approach to adhesive contact indicates an equilibrium surface-charge density σ=σ0 due to the loss of K+ ions from the mica surface into the water. Subsequent force measurements at times τ following separation of the surfaces reveal that σ drops markedly following contact and separation, but then relaxes back to σ0 with a characteristic time τr=11±2 min. This behavior is attributed to condensation of the counterions into the surfaces when they come into contact, and to their subsequent slow release into the water. The energy barrier associated with the counterion release was estimated from the value of τr to be 33±4 kBT.