N‐Formylation of Amines via the Aerobic Oxidation of Methanol over Supported Gold Nanoparticles
- 17 June 2009
- journal article
- research article
- Published by Wiley in ChemSusChem
- Vol. 2 (6), 538-541
- https://doi.org/10.1002/cssc.200800260
Abstract
Dress code: formyl. Gold nanoparticles supported on NiO catalyze the one-pot N-formylation of amines with methanol and molecular oxygen to produce formamide at a selectivity of 90 %. This process generates methyl formate in situ, followed by reaction with amines.Keywords
This publication has 31 references indexed in Scilit:
- Gold Nano-size Effect in Au/SiO2 for Selective Ethanol Oxidation in Aqueous SolutionCatalysis Letters, 2008
- Catalyst Parameters Determining Activity and Selectivity of Supported Gold Nanoparticles for the Aerobic Oxidation of Alcohols: The Molecular Reaction MechanismChemistry – A European Journal, 2007
- Aerobic oxidation of aqueous ethanol using heterogeneous gold catalysts: Efficient routes to acetic acid and ethyl acetateJournal of Catalysis, 2007
- Formation of Acetic Acid by Aqueous‐Phase Oxidation of Ethanol with Air in the Presence of a Heterogeneous Gold CatalystAngewandte Chemie International Edition, 2006
- Formation of Acetic Acid by Aqueous‐Phase Oxidation of Ethanol with Air in the Presence of a Heterogeneous Gold CatalystAngewandte Chemie, 2006
- A Collaborative Effect between Gold and a Support Induces the Selective Oxidation of AlcoholsAngewandte Chemie International Edition, 2005
- A Collaborative Effect between Gold and a Support Induces the Selective Oxidation of AlcoholsAngewandte Chemie, 2005
- When Gold Is Not Noble: Catalysis by NanoparticlesThe Chemical Record, 2003
- Gold on Carbon as a New Catalyst for Selective Liquid Phase Oxidation of DiolsJournal of Catalysis, 1998
- Chemoselective catalytic oxidation of polyols with dioxygen on gold supported catalystsPublished by Elsevier ,1997