5142-Å Transition in Thiophosgene (π* ← n); Rotational Analysis and Excited-State Structure
- 15 June 1970
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 52 (12), 6126-6129
- https://doi.org/10.1063/1.1672915
Abstract
Rotational structure is observed in the 210310410 vibronic band of the lowest singlet transition of thiophosgene (5142 Å). Computer analysis gives three excited‐state moments of inertia, from which, assuming a value for the C–S bond length, an excited‐state structure may be determined.
Keywords
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