Infrared Spectra of the Germyl Halides
- 1 December 1963
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 39 (11), 2908-2922
- https://doi.org/10.1063/1.1734123
Abstract
The infrared spectra of GeH3F, GeH3Cl, GeH3Br, GeH3I, and their fully deuterated analogs have been measured. All the fundamental vibrations have been observed and assigned. Normal coordinate treatments based on both simple valence and Urey—Bradley force fields have been performed. For germyl fluoride, unusually large frequency shifts have been observed to accompany the phase transition from gas to solid.Keywords
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