In(OH)BDC·0.75BDCH2 (BDC = Benzenedicarboxylate), a Hybrid Inorganic−Organic Vernier Structure
- 7 October 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (43), 15000-15001
- https://doi.org/10.1021/ja055757a
Abstract
The compound In(OH)BDC·0.75BDCH2 (BDC = benzenedicarboxylate), 1, has been synthesized and characterized by single-crystal X-ray diffraction. The structure comprises two distinct sublattices formed by a covalently linked In(OH)BDC lattice and ordered chains of hydrogen-bonded H2BDC molecules and can be described as a hybrid inorganic coordination polymer−organic vernier structure. Each InO6 octahedron of the octahedral chain has a length of 3.6 Å along the chain axis, whereas each H2BDC molecule has a length of 9.6 Å along the guest column axis. Therefore, a unit of eight InO6 octahedra of the octahedral chain is just in registry with three H2BDC molecules of the guest column giving a repeat unit of 28.76 Å along the channel axis direction.Keywords
This publication has 14 references indexed in Scilit:
- Novel 2D and 3D Indium Metal-Organic Frameworks: Topology and Catalytic PropertiesChemistry of Materials, 2005
- The Nowotny Chimney Ladder Phases: Following the cpseudo Clue toward an Explanation of the 14 Electron RuleInorganic Chemistry, 2004
- A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL‐53) Upon HydrationChemistry – A European Journal, 2004
- Local Structural Aspects of One-Dimensional Solid Inclusion CompoundsPhase Transitions, 2003
- Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids: MIL-53 or CrIII(OH)·{O2C−C6H4−CO2}·{HO2C−C6H4−CO2H}x·H2OyJournal of the American Chemical Society, 2002
- Advances in the synthesis and structural description of 2H-hexagonal perovskite-related oxidesCurrent Opinion in Solid State and Materials Science, 2001
- Room- and Low-Temperature Crystallographic Study of the Ambient Pressure Organic Superconductor (Bisethylene dithiotetrathiofulvalene)4Hg2.89Br8Chemistry of Materials, 1998
- Synthesis of the new high pressure Vernier phase Sr0.74CuO2Journal of Materials Chemistry, 1995
- Preparation of a New Strontium Titanium Sulfide SrxTiS3 (x = 1.05 - 1.22) with Infinitely Adaptive StructuresJournal of Solid State Chemistry, 1993
- A theoretical study of cooperative dual linear aggregation and the vernier effectBiophysical Chemistry, 1986