A new synthetic approach to quassinoids via an intramolecular Diels-Alder reaction: a stereoselective construction of the klaineanone ring system
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 10,p. 2569-2576
- https://doi.org/10.1039/p19830002569
Abstract
Thermolysis of the benzocyclobutene derivative (25) prepared from norcamphor (6) gave stereoselectively the tetracyclic compound (27), which was converted into the D-deoxyquassinoid derivative (2) possessing the same ABCD-ring fusion as that of klaineanone (1).This publication has 1 reference indexed in Scilit:
- Structural requirements for biological activity among antileukemic glaucarubolone ester quassinoidsJournal of Medicinal Chemistry, 1976