Optical Absorption by Charge-Transfer Excitons in Linear Molecular Crystals

Abstract

The optical absorption of linear molecular crystals is investigated theoretically. A generalization of the theory of excitons in linear molecular crystals was carried out by Merrifield who constructed the excited states of the crystal by mixing monomolecular states (Frenkel excitons) and bimolecular ionized states in which an electron is removed from one molecule in the crystal and placed on a second (charge‐transfer states). If the monomolecular optical transition is allowed, we find that the optical absorption consists of a series of bound states and a continuum absorption, which gives rise to photoconductivity; the strength of all the absorption is predominantly borrowed from the Frenkel exciton. The experimental possibilities may be classified into three cases: (1) the Frenkel exciton, the charge‐transfer state with electron and hole at nearest neighbors, and the state with the electron and hole at large separation are well separated in energy. This case gives rise to a strong absorption line, small charge‐transfer sidebands, and very small absorption into the continuum. (2) Near resonance between Frenkel and nearest‐neighbor charge‐transfer states. The strong absorption is now shared by two absorption lines with weak sidebands and very small continuum absorption. (3) Resonance between the Frenkel state and the states with the electron and hole at large separation. This case corresponds to autoionization in a solid, the bound states have very weak absorption, and a strong sharp line will be observed within the continuum absorption. The width of the resonance line is directly proportional to the background absorption.