Influence of Hydrodynamic Interaction on the Viscoelastic Behavior of Dilute Polymer Solutions
- 1 July 1963
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 39 (1), 149-153
- https://doi.org/10.1063/1.1733992
Abstract
The theory of Zimm for the viscoelastic properties of dilute polymer solutions is expanded into a more general treatment containing both the theories of Rouse and Zimm as limiting cases. This treatment predicts a transition from Zimm‐like to Rouse‐like behavior with changing hydrodynamic interaction. Values of Flory's Φ as a function of the hydrodynamic interaction parameter h are tabulated.Keywords
This publication has 9 references indexed in Scilit:
- Effect of Partial Draining on the Intrinsic Viscosity of Flexible MacromoleculesThe Journal of Chemical Physics, 1962
- VISCOELASTIC PROPERTIES OF DILUTE POLYSTYRENE SOLUTIONS AND VERIFICATION OF THE ZIMM THEORY1The Journal of Physical Chemistry, 1962
- Molecular Weight Distribution of Polymers from Rheological Measurements in Dilute SolutionThe Journal of Chemical Physics, 1961
- Die Einführung statistischer Segmente im Rahmen der Theorie des mechanischen und dielektrischen Relaxationsverhaltens von Makromolekülen in verdünnten LösungenColloid and Polymer Science, 1961
- Computation of Fresnel integralsMathematics of Computation, 1960
- Dynamics of Polymer Molecules in Dilute Solution: Viscoelasticity, Flow Birefringence and Dielectric LossThe Journal of Chemical Physics, 1956
- Solution of a Characteristic Value Problem from the Theory of Chain MoleculesThe Journal of Chemical Physics, 1956
- A Theory of the Linear Viscoelastic Properties of Dilute Solutions of Coiling PolymersThe Journal of Chemical Physics, 1953
- The Intrinsic Viscosities and Diffusion Constants of Flexible Macromolecules in SolutionThe Journal of Chemical Physics, 1948