Spectrum of light scattered from a viscoelastic gel

Abstract

We report measurements of the spectrum of light scattered from thermally excited displacement fluctuations in polyacrylamide gels. These measurements have been carried out on the polarized scattered light as a function of scattering angle and temperature for 5% and 2.5% polyacrylamide gels using the methods of optical mixing spectroscopy. We also present a theory for the amplitude and time dependence of the thermally excited longitudinal and transverse displacements of the gel fiber network. These displacements are responsible, respectively, for the polarized and depolarized scattered light. The correlation function for the displacements having wave vector q is predicted for these gels to have the form of an exponential decay: exp(− Γt). The decay rate is given by Γ = G_lq²/f or G_tq²/f, where f is the frictional force per unit volume on the fiber network as it moves with unit velocity relative to the gel liquid. G_l is the longitudinal compressional modulus for longitudinal displacements and G_t is the shear modulus for transverse displacements of the fiber network. We have measured, using macroscopic methods, the friction factor f, and the elastic moduli G_l, G_t and compared the numerical predictions of the theory with the experimental measurements of the correlation function of the scattered light intensity. The theory is quite successful in predicting the size and q dependence of the decay rate of the time correlation function of the scattered light. Conversely, these experiments demonstrate that the correlation function of the light scattered from thermal fluctuations of the gel fiber network provides a detailed quantitative characterization of the viscoelastic properties of gels.