Reductive Ring Openings of Carbohydrate Benzylidene Acetals Using Borane-Trimethylamine and Aluminium Chloride. Regioselectivity and Solvent Dependance
- 1 January 1983
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 2 (3), 305-311
- https://doi.org/10.1080/07328308308057876
Abstract
Regioselective reductive ring openings of 4, 6-O-benzylidene acetals of hexopyranosides are described using borane trimethylamine-aluminium chloride. Using toluene as solvent, 4-O-benzyl ethers with the 6-OH free are obtained. Using tetrahydrofuran as solvent. 6-O-benzyl ethers with the 4-OH free are obtained.This publication has 18 references indexed in Scilit:
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