Oxidative Addition of Ammonia at a Silicon(II) Center and an Unprecedented Hydrogenation Reaction of Compounds with Low-Valent Group 14 Elements Using Ammonia Borane
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- 18 March 2009
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 131 (13), 4600-4601
- https://doi.org/10.1021/ja900880z
Abstract
The reaction of L′Si [L′ = CH{(C═CH2)(CMe)(2,6-iPr2C6H3N)2}] with ammonia under oxidative addition results in L′Si(H)NH2. H3NBH3 functions as a source of hydrogen for the hydrogenation of N-heterocyclic carbenes and germylenes.Keywords
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