Neue Enzymmodelle für die Chlorperoxidase — Synthesen und katalytische Reaktionen
- 14 February 1997
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 109 (4), 404-407
- https://doi.org/10.1002/ange.19971090425
Abstract
Das Eisen(III)‐porphyrin 1 katalysiert die Chlorierung aktivierter C‐H‐Bindungen und ist demnach eine Modellverbindung für ein bisher nicht identifiziertes Zwischenprodukt des katalytischen Cyclus des Häm‐Thiolat‐Proteins Chlorperoxidase. An den Chlorierungen ist vermutlich weder freies HOCl noch Cl. beteiligt; als Cl+‐Donor wirkt statt dessen das an FeIII gebundene HOCl. magnified imageThis publication has 25 references indexed in Scilit:
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