The Reactions of Silicon Tetrachloride with Catechol and 2,2?-Dihydroxybiphenyl
- 1 January 1972
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 2 (2), 97-104
- https://doi.org/10.1080/00945717208069587
Abstract
The reaction between silicon tetrachloride and catechol in acetonitrile at 0° results in the formation of o-phenylenedioxydichlorosilane (I) and bis(o-phenylenedioxy)silane (III). The former compound exists both as a monomer-dimer mixture (I and II) and as the pure dimer (II). 2,2′-Biphenylenedioxy-bis(methoxy)silane (V) was also prepared and its facile conversion to bis(2,2′-biphenylenedioxy)silane (VI) was observed.Keywords
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