Indium-Mediated Reduction of Hydroxylamines to Amines
- 22 April 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 5 (10), 1773-1776
- https://doi.org/10.1021/ol034434l
Abstract
A novel and simple procedure for reduction of hydroxylamines to the corresponding amines by means of indium powder in aqueous media is reported. Applicability to one-pot reactions and isoxazolidine N−O bond reduction is also demonstrated. A catalytic version of the process using 2−5% In in the presence of other metals (Zn, Al) has been successfully developed.Keywords
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