Reaction of Elemental Sulfur with a Copper(I) Complex Forming a trans-μ-1,2 End-On Disulfide Complex: New Directions in Copper−Sulfur Chemistry
- 14 January 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 125 (5), 1160-1161
- https://doi.org/10.1021/ja027574j
Abstract
Elemental sulfur (S8) was found to react with [(TMPA)CuI(CH3CN)]+ to form the trans-μ-1,2 end-on disulfide complex [(TMPA)Cu−S−S−Cu(TMPA)]2+. The X-ray structure of this centrosymmetric disulfide complex shows a Cu(1)−S(1) bond length of 2.280(2) Å and a S(1)−S(1A) bond length of 2.044(4) Å.Keywords
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