ORGANOGERMANIUM COMPOUNDS: PART I. THE INTERACTION OF HEXAMETHYLDIGERMOXANE AND TRIMETHYLMETHOXYGERMANE WITH BORON TRIFLUORIDE

Abstract

Boron trifiuoride does not form a stable adduct with hexamethyldigermoxane. Instead, cleavage of the Ge—O—Ge linkage occurs with quantitative formation of trimethylfluorogermane and boron trioxide. Trimethylmethoxygermane and boron trifiuoride form a 1:1 addition compound which sublimes without decomposition. Dative d_π–p_π bonding, if present in the Ge—O linkage of trimethylmethoxygermane, does not appear to affect appreciably the electron-donor activity of the oxygen atom toward boron trifiuoride. The preparation and some properties of CH₃GeH₂Br, CH₃GeHCl₂, (CH₃)₃GeCl, (CH₃)₃GeF, [(CH₃)₃Ge]₂O, and (CH₃)₃GeOCH₃ are described.