Abstract
The energies of the 4f3d atomic transitions in pionic calcium and titanium have been measured with a bent-crystal spectrometer, and were found to be 72.352±0.009 and 87.651±0.009 keV, respectively. The relationship of these transition energies to the mass of the negatively charged pion is calculated. Comparison of the measurement with the calculation yields Mπc2=139.577±0.013 MeV as a new estimate of the charged-pion mass. Conservation of energy and momentum in the πμ+ν decay process is examined, and an upper limit of 2.1 MeV (68% confidence level) is assigned to the mass of the muon neutrino. The π mass measurement reported here is compared with an earlier measurement of the π+ mass as a test of CPT invariance. We find Mπ+Mπ=1.0002±0.0004.

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