Length dependence of the second-order optical nonlinearity in conjugated hydrocarbons
- 1 February 1981
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 74 (3), 1559-1563
- https://doi.org/10.1063/1.441296
Abstract
Experimental results and a theoretical model are presented which give strong evidence that the ratio β/L2μM is a constant for a large class of disubstituted conjugated hydrocarbons, β is the second-order polarizability, μM the mesomeric dipole moment, and L the length of the hydrocarbon chain.Keywords
This publication has 16 references indexed in Scilit:
- A new class of conjugated molecules with large second order polarizabilityOptics Communications, 1978
- Ester enolate Claisen rearrangement. Construction of the prostanoid skeletonThe Journal of Organic Chemistry, 1976
- Theory of second-order optical susceptibilities of benzene substitutesOptics Communications, 1975
- Third-order optical polarizability of conjugated organic moleculesOptics Communications, 1974
- Olefin synthesis with organic phosphonate carbanionsChemical Reviews, 1974
- Measurements of hyperpolarizabilities for some halogenated methanesThe Journal of Chemical Physics, 1974
- Mesure des interactions entre ondes lumineuses dans diverses substancesJournal de Physique, 1971
- 888. The electric dipole moments of a vinylenic seriesJournal of the Chemical Society, 1958
- 625. Polarisation in conjugated systems. Part IV. Mesomeric momentsJournal of the Chemical Society, 1951
- The significance of the differences between the dipole moments of saturated and unsaturated substancesProceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character, 1931