Crystal structure and isothermal compression of Fe2O3, Cr2O3, and V2O3 to 50 kbars

Abstract

Crystal structures of several of the corundum‐type oxides have been determined at pressures to 50 kbars. All materials have linear compression within the pressure range and precision of the techniques used. Compression of Cr₂O₃ and Al₂O₃ is essentially isotropic (c/a remains constant), Fe₂O₃ has a slightly anisotropic compression, with c/a decreasing slightly with pressure, and V₂O₃ is very anisotropic, with the a axis nearly three times more compressible than c. Similar differences are observed in the structural parameters. Aluminum, iron, and chromium sesquioxides simply scale, whereas atomic positions in V₂O₃ approach an ideal HCP arrangement with increasing pressure. The differences in structural variation with pressure for these ’’isostructural’’ compounds emphasize the difficulty in using simple bonding parameters to predict details of crystal structures under nonambient conditions.