Analytical relativistic self-consistent-field calculations for atoms
- 1 June 1980
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 21 (6), 1773-1785
- https://doi.org/10.1103/physreva.21.1773
Abstract
A new second-order representation of the Dirac equation is presented. This representation which is exact for a hydrogen atom is applied to approximate analytical self-consistent-field calculations for atoms. Results are given for the rare-gas atoms from helium to radon and for lead. The results compare favorably with numerical Dirac-Hartree-Fock solutions.Keywords
This publication has 12 references indexed in Scilit:
- A new general methodology for deriving effective Hamiltonians for atoms and molecules. Application to the transferability of atomic potentials in the hydrocarbon seriesThe Journal of Chemical Physics, 1980
- A new general methodology for deriving transferable atomic potentials in moleculesThe Journal of Chemical Physics, 1979
- Approximate relativistic corrections to atomic radial wave functions*Journal of the Optical Society of America, 1976
- Roothaan-Hartree-Fock atomic wavefunctionsAtomic Data and Nuclear Data Tables, 1974
- Relativistic Effects in The Many-Electron AtomPublished by Elsevier ,1974
- Relativistic calculation of atomic structuresAdvances in Physics, 1970
- Relativistic Theory of Radiative Orbital Electron CapturePhysical Review B, 1958
- Theory of the Fermi InteractionPhysical Review B, 1958
- Quantum Mechanics of One- and Two-Electron AtomsPublished by Springer Nature ,1957
- New Developments in Molecular Orbital TheoryReviews of Modern Physics, 1951