REACTION OF OXYGEN ATOMS WITH BUTADIENE
- 1 November 1960
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 38 (11), 2187-2195
- https://doi.org/10.1139/v60-296
Abstract
Reaction of oxygen atoms with 1,3-butadiene has been investigated at room temperature. It is found that it conforms to the general mechanism established previously for the analogous reactions of monoolefins. Only 1,2-addition occurs, and the addition products, butadiene monoxide and 3-butenal, possess excess energy when formed as a result of high heats of reaction. The pressure dependence of the formation of the addition products yields the values of the "lifetimes" of the initially produced "hot" molecules. The relative rate constants have been determined at 25 and 127 °C and from these the relative values of the Arrhenius parameters have been calculated.Keywords
This publication has 4 references indexed in Scilit:
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- PHOTOÖXIDATION OF BUTENE-1 AND ISOBUTENE BY NITROGEN DIOXIDECanadian Journal of Chemistry, 1958
- MOLECULAR REARRANGEMENTS IN THE REACTIONS OF OXYGEN ATOMS WITH OLEFINSCanadian Journal of Chemistry, 1958
- Reaction of Oxygen Atoms with EthyleneThe Journal of Chemical Physics, 1955