An infinite square lattice of super-supertetrahedral T6-like tin oxyselenide clusters
- 27 February 2014
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 50 (31), 4044-4046
- https://doi.org/10.1039/c4cc00583j
Abstract
A new super-supertetrahedral cluster, resembling a coreless supertetrahedral T6 cluster, was made as a tin oxyselenide by integrating hard and soft Lewis bases (O2− and Se2−) into the tetravalent system. Its hierarchical architecture, built from supertetrahedral T3-[Sn10O4Se20] and Sn2Se6 clusters, represents a new level of complexity in the cluster-based construction. Compared to pure tin selenides, the new tin oxyselenide material in this work shows much enhanced stability and size-dependent band energy level.This publication has 36 references indexed in Scilit:
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