A Strongly Emitting Liquid‐Crystalline Derivative of Y3N@C80: Bright and Long‐Lived Near‐IR Luminescence from a Charge Transfer State
- 7 October 2013
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 52 (47), 12303-12307
- https://doi.org/10.1002/anie.201305536
Abstract
Great balls of fire: C60 and Y3N@C80 were connected to the same oligo(phenyleneethynylene) unit to investigate their structural and photophysical properties. NMR investigations revealed a fulleroid structure for the Y3N@C80 derivative, and both dyads gave rise to columnar phases with core‐shell cylinders. The black and gray spheres represent the fullerene core units of the Y3N@C80 derivative, which is an ideal candidate to be involved in energy and electron transfer processes.Keywords
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