CHEMISTRY OF THE TRIFLUOROMETHYL GROUP: PART III. PHENYLBISTRIFLUOROMETHYLPHOSPHINE AND RELATED COMPOUNDS
- 1 March 1961
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 39 (3), 564-570
- https://doi.org/10.1139/v61-068
Abstract
The reaction of trifluoroiodomethane with tetraphenylcyclotetraphosphine leads to the formation of phenylbistrifluoromethylphosphine and phenyltrifluoromethyliodophosphine. The mechanism of the reaction is discussed and the physical and chemical properties of these compounds are reported. Bromine reacts with phenylbistrifluoromethylphosphine to form phenylbistrifluoromethyldibromophosphorane which is hvdrolyzed to phenyltrifluoromethylphosphinic acid, C6H5(CF3)P(O)OH.Keywords
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