Thermodynamic Properties of the Solvent Extraction of Anions with TRIS(1,10-Phenanthroline)iron(II) Chelate Cations
- 1 January 1969
- journal article
- research article
- Published by Taylor & Francis in Analytical Letters
- Vol. 2 (1), 1-7
- https://doi.org/10.1080/00032716908051265
Abstract
Thermodynamic quantities were determined for the extraction of ion pairs of tris(1,10-phenanthroline) iron(II) chelate cations with halide, thiocyanate and perchlorate anions from aqueous phase into nitrobenzene. Ion pairs with larger anions have more negative enthalpy changes with higher extractability. For bromide, the enthalpy change was found to be almost zero and a positive change was observed for chloride. Entropy changes are also discussed.Keywords
This publication has 3 references indexed in Scilit:
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