Theory of the Linear Electric Field Effect on the Electron-Paramagnetic-Resonance Spectra ofIons in ZnS
- 1 September 1971
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 4 (5), 1444-1451
- https://doi.org/10.1103/physrevb.4.1444
Abstract
The linear effect of an external electric field on the EPR spectra of ions in cubic crystals is described by a third-rank tensor with only one independent component. The values of this parameter are calculated from a molecular-orbital theory for , , and in ZnS (zinc blende). Very good agreement with experiment is obtained by a mechanism in which charge-transfer levels and ligand orbitals play a dominant role.
Keywords
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