Decamethylmanganocenium tetracyanoethenide, [Mn(C5Me5)2]⊙⊙⊕ [TCNE]⊙⊖—a molecular ferromagnet with an 8.8 K Tc
- 1 June 1991
- journal article
- research article
- Published by Wiley in Advanced Materials
- Vol. 3 (6), 309-311
- https://doi.org/10.1002/adma.19910030609
Abstract
Communication: Triplet electron‐transfer salts are predicted to exhibit bulk ferromagnetic behavior at higher temperatures than their singlet analogues. To test this expected trend, the title compound, which is isostructural with [FeCp]⊙⊕ [TCNE]⊙⊖ (Cp* = pentamethylcyloopentadienide; TCNE = tetracyanoethylene) which exhibits a Curie temperature, Tc, of 4.8 K has been synthesized. The synthesis and magnetic characterization of the new compound, which is found to have aTc of 8.8 K, are reported.This publication has 14 references indexed in Scilit:
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