Ion-molecule reactions in CO2and CO2-CO mixtures
- 11 May 1977
- journal article
- Published by IOP Publishing in Journal of Physics D: Applied Physics
- Vol. 10 (7), 969-977
- https://doi.org/10.1088/0022-3727/10/7/003
Abstract
Rates for the formation of positive CO2 cluster ions by the following reaction have been measured over a wide range of the parameter E/N: CO2++2CO2 to or from (CO2.CO2)++CO2. Additions of small amounts of CO cause a marked change in the ion species detected and these are interpreted as follows: (CO2.CO2)++CO to (CO2.CO)++CO2 and (CO2.CO)++CO to (CO.CO)++CO2. Measurements with labelled CO have confirmed these conclusions.Keywords
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