The interaction of rare gas atoms with graphite surfaces. II. Adatom–adatom potentials
- 1 June 1975
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 62 (11), 4300-4307
- https://doi.org/10.1063/1.430351
Abstract
The Gordon–Kim local density method is applied to the calculation of the interaction energy of pairs of neon, argon, and krypton atoms adsorbed on the basal plane of graphite. At the adatom–surface equilibrium separation, the adatom–adatom interaction potentials are found to be from 12% to 20% more repulsive than the gas phase counterparts. At much smaller adatom–surface separations, the adatom–adatom effective potential well depth is only 3% of the gas phase well depth. It is found that the nonadditive contributions to the interaction energy are more important for the smaller rare gas adatoms than for the larger ones. This trend is observed experimentally. It is concluded that rare gas films on graphite are too mobile to be in registry with the substrate.Keywords
This publication has 19 references indexed in Scilit:
- Nonadditive three-body interactions of rare-gas atoms. II. Intermediate and large distancesPhysical Review A, 1975
- Nonadditive three-body interactions of rare-gas atoms. I. Small and intermediate distancesPhysical Review A, 1975
- Effect of nonadditive forces on the binding of closed-shell adsorbates on closed-shell substrates. I. Ar/Ar(100)Physical Review B, 1974
- Phases ofandMonolayer Films Adsorbed on Basal-Plane Oriented GraphitePhysical Review A, 1973
- Many-Body Aspects of Physical AdsorptionThe Journal of Chemical Physics, 1971
- Applications of McLachlan's theory to physical adsorptionThe Journal of Physical Chemistry, 1968
- Interactions between physically adsorbed moleculesTransactions of the Faraday Society, 1967
- Interactions between adsorbed moleculesDiscussions of the Faraday Society, 1965
- Forces between adsorbed atoms and the determination of surface areas of solidsTransactions of the Faraday Society, 1964
- High temperature adsorption and the determination of the surface area of solidsTransactions of the Faraday Society, 1962