Dynamics of intramolecular vibrational-energy redistribution (IVR). II. Excess energy dependence
- 1 April 1985
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 82 (7), 2975-2993
- https://doi.org/10.1063/1.448247
Abstract
The results of picosecond‐resolved measurements of intramolecular vibrational‐energy redistribution (IVR) in jet‐cooled anthracene at different excess energies are presented. From these results, the nature of IVR as a function of vibrational energy, the relevant time scales for the process, and the details of pertinent vibrational couplings are determined.Keywords
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