Catalytic Pauson−Khand-Type Reaction Using Aldehydes as a CO Source
- 9 April 2002
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 4 (9), 1619-1621
- https://doi.org/10.1021/ol025836g
Abstract
Rhodium complex-catalyzed carbonylative alkene−alkyne coupling proceeds using aldehydes as a CO source. Cinnamaldehyde is the best CO donor, and various cyclopentenones were provided in high isolated yields by a solvent-free system.Keywords
This publication has 6 references indexed in Scilit:
- Room-Temperature Ionic Liquids. Solvents for Synthesis and CatalysisChemical Reviews, 1999
- Homogeneous Catalysis in Supercritical FluidsChemical Reviews, 1999
- Amyloid Aggregates, Presenilins, and Alzheimer's DiseaseAngewandte Chemie International Edition, 1998
- Selective activation of carbon–carbon bonds next to a carbonyl groupNature, 1994
- Metal-catalyzed decarbonylation of primary aldehydes at room temperatureThe Journal of Organic Chemistry, 1992
- Synthesis and study of pseudo-aromatic compounds. VI. Synthesis of 6,7-dihydrocyclohepta[de]naphthalene and a conformational analysis of 1,2-benzoheptafulveneJournal of the American Chemical Society, 1968