Dissociation of tris(triphenylphosphine)chlorohodium(I) in solution

1 January 1971

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications

No. 23,p. 1571-1572
https://doi.org/10.1039/c29710001571

Abstract

The equilibrium constant for the dissociation of RhCl(PPh₃)₃ according to the reaction, RhCl(PPh₃)₃⇌ RhCl(PPh₃)₂+ PPh₃, has been determined spectrophotometrically to be (1·4 ± 0·4)× 10^–-4 M in benzene solution at 25°.

Keywords

TRIS
TRIPHENYLPHOSPHINE
CHLOROHODIUM
BENZENE
SPECTROPHOTOMETRICALLY
EQUILIBRIUM
DISSOCIATION
RHCL
PPH3

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