Enantioselective Ring Opening of Meso Aziridines Catalyzed by Tridentate Schiff Base Chromium(III) Complexes
- 17 October 1999
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 1 (10), 1611-1613
- https://doi.org/10.1021/ol990992h
Abstract
A catalytic method for the enantioselective ring opening of meso aziridines by TMSN3 is described. Tridentate Schiff base chromium complexes derived from 1-amino-2-indanol were identified as the optimal catalysts.Keywords
This publication has 9 references indexed in Scilit:
- Highly Enantio- and Diastereoselective Hetero-Diels-Alder Reactions Catalyzed by New Chiral Tridentate Chromium(III) CatalystsAngewandte Chemie International Edition, 1999
- The Chemistry of Vicinal DiaminesAngewandte Chemie International Edition, 1998
- Practical Synthesis of Enantiopure Cyclic 1,2-Amino Alcohols via Catalytic Asymmetric Ring Opening of Meso EpoxidesThe Journal of Organic Chemistry, 1997
- The asymmetric synthesis of aziridinesTetrahedron: Asymmetry, 1997
- Enantioselective desymmetrisation of achiral epoxidesTetrahedron, 1996
- Kinetic Resolution of Terminal Epoxides via Highly Regioselective and Enantioselective Ring Opening with TMSN3. An Efficient, Catalytic Route to 1,2-Amino AlcoholsJournal of the American Chemical Society, 1996
- Highly Enantioselective Ring Opening of Epoxides Catalyzed by (salen)Cr(III) ComplexesJournal of the American Chemical Society, 1995
- Chiral Aziridines—Their Synthesis and Use in Stereoselective TransformationsAngewandte Chemie International Edition in English, 1994
- Yb(CN)3-catalyzed reaction of aziridines with cyanotrimethylsilane. A facile synthesis of optically pure β-amino nitrilesTetrahedron Letters, 1990