Monomer Reactivity Ratios from High Conversion Copolymerization of Styrene with meta- and with para-Divinylbenzene
- 1 November 1970
- journal article
- research article
- Published by Informa UK Limited in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 4 (7), 1453-1462
- https://doi.org/10.1080/00222337008069362
Abstract
The copolymerization reactivity ratios for styrene/m- and styrene/p-divinylbenzene have been determined at high conversions (1 (s) = 1.11, r2 (m) = 1.00; and r1 (s) = 0.20, r2 (p) = 1.00 were obtained. These values indicate the same relative behavior but are quantitatively different from the differential data. The data confirm that the para isomer is incorporated more rapidly into the growing polymer chain than is the meta isomer.Keywords
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