Preparation of Tris(p-chlorophenylisocyanide)bis(trimethylphosphite)cobalt(I) Tetrafluoroborate and Tris(p-chlorophenylisocyanide)bis(triphenylphosphine)cobalt(I) Perchlorate
- 1 January 1974
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 4 (3), 213-219
- https://doi.org/10.1080/00945717408069657
Abstract
Two molecules of p-ClC6H4NC in [Co(CNC6H4Cl-4)5]ClO4, BF4 are immediately replaced by P(OCH3)3 and P(C6H5)3 under mild, unprotected reaction conditions. Initial characterization by ir and NMR is compatible with trigonal bipyramidal structures.Keywords
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