Strongly Basic Proazaphosphatranes: P (EtNCH2CH2)3N and P (iso-PrNCH2CH2)3N
- 1 September 1995
- journal article
- research article
- Published by IOS Press in Main Group Chemistry
- Vol. 1 (1), 69-79
- https://doi.org/10.1080/13583149512331338275
Abstract
The two new azaphosphatranes HP(RNCH2 CH2 )3 N+ Cl− (R = Et, 2c and R = i-Pr, 2d) were prepared from the corresponding (RNHCH2 CH2 )3 N and CIP(NEt2 )2 . They were transformed into the title proazaphosphatranes 3c and 3d, respectively, with tert-BuOKKeywords
This publication has 26 references indexed in Scilit:
- Nonionic Superbase-Promoted Synthesis of Oxazoles and Pyrroles: Facile Synthesis of Porphyrins and .alpha.-C-Acyl Amino Acid EstersThe Journal of Organic Chemistry, 1994
- HETERYLGERMATRANESMain Group Metal Chemistry, 1994
- Metallation of multifunctional secondary amines: the structural characterisation of the tripodal lithium amides {H3CC[CH2N(Li)R]3}3J. Chem. Soc., Dalton Trans., 1993
- Monomeric and dimeric titanatranesInorganic Chemistry, 1991
- The "anomalous" basicity of P(NHCH2CH2)3N relative to P(NMeCH2CH2)3N and p(NBzCH2CH2)3N: a chemical consequence of orbital charge balance?Journal of the American Chemical Society, 1990
- Preparation of triaza-, tetraaza- and peraza-crown compounds containing aminoalkyl side groups or unsubstituted ring nitrogen atomsThe Journal of Organic Chemistry, 1990
- New azasilatranes: sterically induced transannular bond weakening and cleavageJournal of the American Chemical Society, 1989
- The unusually robust phosphorus-hydrogen bond in the novel cation [cyclic] HP(NMeCH2CH2)3N+Journal of the American Chemical Society, 1989
- Structural Studies on the Phosphorus--Nitrogen Bond. I. The Crystal Structure of Tris(morpholino)phosphine and Tris(piperidino)phosphine.Acta Chemica Scandinavica, 1978
- Exchange of Parts between Molecules at Equilibrium. III. Nonrandom Redistribution of Dialkylamino Groups and halogens on Triply Connected PhosphorusJournal of the American Chemical Society, 1964